Synthesis, Crystal Structure and Characterization of α-(1-Benzimidazolyl)-hypnone Cobalt(Ⅱ) Complex:[CoCl(C7H5N2CH2COPh)

The crystal structure of [CoCl(C7H5N2CH2COPh)4]Br has been determined by means of X-ray crystallography. The molecular structure consists of a discrete [CoCl(C7H5N2CH2COPh)4]+ cation and one Br- anion. In the [CoCl(C7H5N2CH2COPh)4]+ cation, the coordination geometry of the central Co atom is square-pyramidal with four tertiary N atoms of benzimidazole from four α-(benzimidazol-1-yl)-hypnone ligands in the basal position and one chloride anion in the apical position. In the solid state, [CoCl(C7H5N2CH2COPh)4]+ and Br- anion possess intermolecular and intramolecular interactions, which stabilize the crystal structure. The characterization of the title compound were also carried out by using elemeutal analysis, FTIR, UV spectrometries and TG-DSC.

作 者： JIAN Fang-Fang SUN Ping-Ping XIAO Hai-Lian ZHAO Pu-Su   作者單位： New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao 266042, P. R. China  刊 名： 高等學(xué)�；瘜W(xué)研究（英文版）  ISTIC SCI 英文刊名： CHEMICAL RESEARCH IN CHINESE UNIVERSITIES  年，卷(期)： 2005 21(4)  分類(lèi)號(hào)： O6  關(guān)鍵詞： α-(1-Benzimidazolyl)-hypnone ligand   Cobalt(Ⅱ) complex   Mixed Cl- and Br- anion   TG-DSC  

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